The use of redox-active organic molecules and magnetic metal ions as molecular building blocks for materials represents a new strategy towards novel types of 2D materials exhibiting both high electronic conductivity and magnetic order. Credit: Kasper Steen Pedersen and We Love People.
An international team led by Assistant Professor Kasper Steen Pedersen, DTU Chemistry, has synthesized a novel nano material with electrical and magnetic properties making it suitable for future quantum computers and other applications in electronics.
Chromium-chloride-pyrazine (chemical formula CrCl2(pyrazine)2) is a layered material, which is a precursor for a so-called 2-D material. In principle, a 2-D material has a thickness of just a single molecule and this often leads to properties very different from those of the same material in a normal 3-D version; not least of which, the electrical properties will differ. While in a 3-D material, electrons are able to take any direction, in a 2-D material they will be restricted to moving horizontally—as long as the wavelength of the electron is longer than the thickness of the 2-D layer.
Organic/inorganic hybrid
Graphene is the most well-known 2-D material. Graphene consists of carbon atoms in a lattice structure, which yields its remarkable strength. Since the first synthesis of graphene in 2004, hundreds of other 2-D materials have been synthesized, some of which may be candidates for quantum electronics applications. However, the novel material is based on a very different concept. While the other candidates are all inorganic—just like graphene—chromium-chloride-pyrazine is an organic/inorganic hybrid material.
"The material marks a new type of chemistry, in which we are able to replace various building blocks in the material and thereby modify its physical and chemical properties. This cannot be done in graphene. For example, one can't choose to replace half the carbon atoms in graphene with another kind of atom. Our approach allows designing properties much more accurately than known in other 2-D materials," Kasper Steen Pedersen explains.
The use of redox-active organic molecules and magnetic metal ions as molecular building blocks for materials represents a new strategy towards novel types of 2D materials exhibiting both high electronic conductivity and magnetic order. Credit: Kasper Steen Pedersen and We Love People.
Besides the electrical properties, also the magnetic properties in Chromium-Chloride-Pyrazine can be accurately designed. This is especially relevant in relation to "spintronics".
"While in normal electronics, only the charge of the electrons is utilized, But also electron spin—which is a quantum mechanical property—is used in spintronics. This is highly interesting for quantum computing applications. Therefore, development of nano-scale materials which are both conducting and magnetic is most relevant," Kasper Steen Pedersen notes.
A new world of 2-D materials
Besides quantum computing, chromium-chloride-pyrazine may be of interest in future superconductors, catalysts, batteries, fuel cells, and electronics in general.
Companies are not keen to begin producing the material right away, the researcher stresses: "Not yet, at least! This is still fundamental research. Since we are suggesting a material synthesized from an entirely novel approach, a number of questions remain unanswered. For instance, we are not yet able to determine the degree of stability of the material in various applications. However, even if chromium-chloride-pyrazine should for some reason prove unfit for the various possible applications, the new principles behind its synthesis will still be relevant. This is the door to a new world of more advanced 2-D materials opening up."
More information: Kasper S. Pedersen et al, Formation of the layered conductive magnet CrCl2(pyrazine)2 through redox-active coordination chemistry, Nature Chemistry (2018). DOI: 10.1038/s41557-018-0107-7
Journal information: Nature Chemistry
Provided by Technical University of Denmark
